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Global warming potential explained

Refrigerants and the environment3 min read

The short answer

Global warming potential (GWP) compares how much a gas warms the climate with the same mass of carbon dioxide, usually over 100 years. A refrigerant's GWP shows how much harm a leak would do, and it underpins the rules on refrigerants.

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Refrigerant does no harm while it stays sealed inside an air conditioner. The concern is what happens if it escapes. Global warming potential, or GWP, is the number used to compare that risk between refrigerants, and it sits behind many of the rules about how they're used.

What GWP measures

GWP compares the warming effect of a gas with that of carbon dioxide, which has a GWP of 1 by definition. A gas with a GWP of 675 traps about 675 times as much heat as the same mass of carbon dioxide over the period measured, usually 100 years.

Two things give a gas a high GWP: how strongly it absorbs heat, and how long it stays in the atmosphere before breaking down.

The GWP of common refrigerants

Refrigerant Type GWP
R22 HCFC, no longer allowed for servicing 1,810
R410A HFC blend 2,088
R32 HFC 675
R290 (propane) Natural refrigerant 3
Carbon dioxide Reference gas 1

The HFC figures are the ones used in the F-gas rules in Great Britain. R22 isn't an F-gas: as an ozone-depleting HCFC it falls under separate rules. Scientific assessments are updated from time to time and give slightly different figures, so you may see other numbers quoted elsewhere.

From GWP to CO2-equivalent

GWP turns a mass of refrigerant into a CO2-equivalent: the amount of carbon dioxide that would have the same warming effect. Multiply the mass by the GWP.

Amount of refrigerant CO2-equivalent
1 kg of R32 675 kg
1 kg of R410A 2,088 kg
1 kg of R290 3 kg

So if a system lost 1 kg of R410A, the effect on the climate would be roughly the same as releasing two tonnes of carbon dioxide. The same loss from an R32 system would have about a third of that effect.

How GWP shapes the rules

In Great Britain, the F-gas rules use CO2-equivalent rather than kilograms for many of their thresholds. Mandatory leak checks, for example, apply to systems holding 5 tonnes CO2-equivalent or more.

Refrigerant Amount that reaches 5 tonnes CO2e
R410A About 2.4 kg
R32 About 7.4 kg

A typical home split system holds roughly 0.5 to 1.5 kg of R32, far below that threshold.

The rules also reduce the amount of high-GWP refrigerant that can be sold over time. Rules on high-GWP refrigerants are tightening, which is the main reason manufacturers moved from R410A to R32, and why lower-GWP options, including natural refrigerants, are becoming more common.

Where you'll see it

Equipment containing an F-gas refrigerant carries a label saying so. It names the refrigerant and gives the amount both in kilograms and in tonnes of CO2-equivalent, so you can see a system's refrigerant in climate terms without doing the sum yourself. On an air conditioner, it's usually on or near the outdoor unit's rating plate.

What GWP doesn't tell you

GWP describes the refrigerant, not the whole system. It says nothing about how much electricity a system uses, which is the other part of its effect on the climate, and nothing about how likely it is to leak. A well-installed system that never leaks releases none of its refrigerant while it's in use.

To see both parts together, air conditioning and carbon emissions looks at electricity use and refrigerant side by side.

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